Photocapacitive CdS/WO_x nanostructures for solar energy storage.

ABSTRACT: Through a facile solvothermal procedure, a CdS/WO_x nanocomposite has been synthesised which exhibits photocapacitive behaviour under white light illumination at a radiant flux density of 99.3 mW cm^-2. Photoelectrochemical experiments were undertaken to examine the self-charging properties of the material and to develop an understanding of the underlying electronic band structure responsible for the phenomenon. By employing XPS, UPS and UV-Vis diffuse reflectance spectroscopy for further characterisation, the ability of the composite to generate current following the removal of incident light was related to the trapping of photoexcited electrons by the WO_x component. The presence of WO_x yielded an order of magnitude increase in the transient photo

SUBMITTER: Jones DR 

PROVIDER: S-EPMC6688992 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature