Iron and Nickel Mixed Oxides Derived From Ni^IIFe^II-PBA for Oxygen Evolution Electrocatalysis.

ABSTRACT: The sluggish kinetics of oxygen evolution reaction (OER) on anode hinders the efficiency of electrochemical water splitting. Electrocatalysts for OER based on non-precious transition metals are highly desirable. Herein, iron and nickel mixed oxides with surface oxygen vacancies were fabricated using Ni^IIFe^II-Prussian blue analog as the precursors by a facile two-step thermal-assisted method. The precursor compositions and calcination temperatures exert great impact on the structure and morphology of the derivatives, as well as the electrocatalytic performances for OER. Both the higher content of Ni ions during the synthesis of precursors and lower calcination temperature favor the electrocatalytic performance of the corresponding derivatives. The porous metal oxides c

SUBMITTER: Xie Z 

PROVIDER: S-EPMC6689985 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature