Crystal structure of tetra-μ-acetato-bis-[(5-amino-2-methyl-sulfanyl-1,3,4-thia-diazole-κN 1)copper(II)].
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ABSTRACT: The reaction of 2-methyl-thio-5-amino-1,3,4-thia-diazole (Me-SNTD; C3H5N3S2) with copper(II) acetate monohydrate [Cu(OAc)2·H2O; C4H8CuO5] resulted in the formation of the title binuclear compound, [Cu2(C2H3O2)4(C3H5N3S2)2] or [Cu2(OAc)4(Me-SNTD)2]. The structure has triclinic (P ) symmetry with a crystallographic inversion centre located at the midpoint of the line connecting the Cu atoms in the dimer. These two Cu atoms of the dimer [Cu⋯Cu = 2.6727 (6) Å] are held together by four carboxyl-ate groups. Each Cu atom is further coordinated to the
SUBMITTER: Torambetov B
PROVIDER: S-EPMC6690473 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
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