Layered double hydroxide/sepiolite hybrid nanoarchitectures for the controlled release of herbicides.

ABSTRACT: In this work, organic-inorganic hybrid nanoarchitectures were prepared in a single coprecipitation step by assembling magnesium-aluminum layered double hydroxides (MgAl-LDH) and a sepiolite fibrous clay, with the simultaneous encapsulation of the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA) as the MgAl-LDH retains its ion exchange properties. The synthetic procedure was advantageous in comparison to the incorporation of MCPA by ion exchange after the formation of the LDH/sepiolite nanoarchitecture in a previous step, as it was less time consuming and gave rise to a higher loading of MCPA. The resulting MCPA-LDH/sepiolite nanoarchitectures were characterized by various physicochemical techniques (XRD, FTIR and ²⁹Si NMR spectroscopies, CHN analysis and SEM) that revealed i

SUBMITTER: Rebitski EP 

PROVIDER: S-EPMC6693401 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature