Steering the Self-Assembly Outcome of a Single NDI Monomer into Three Morphologically Distinct Supramolecular Assemblies, with Concomitant Change in Supramolecular Polymerization Mechanism.

ABSTRACT: Noncovalent self-assembly creates an effective route to highly sophisticated supramolecular polymers with tunable properties. However, the outcome of this assembly process is highly dependent on external conditions. In this work, a monomeric naphthalene diimide (NDI), designed to allow solubility in a wide range of solvents, can assemble into three distinct noncovalent supramolecular species depending on solvent composition and temperature. Namely, while the self-assembly in chlorinated solvents yields relatively short, hydrogen-bonded nanotubes, the reduction of solvent polarity changes the assembly outcome, yielding π-π stacking polymers, which can further bundle into a more complex aggregate. The obtained polymers differ not only in their global morphology but-more strikingly-also in th

SUBMITTER: Markiewicz G 

PROVIDER: S-EPMC6702645 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature