Mechanical-force-induced non-local collective ferroelastic switching in epitaxial lead-titanate thin films.

ABSTRACT: Ferroelastic switching in ferroelectric/multiferroic oxides plays a crucial role in determining their dielectric, piezoelectric, and magnetoelectric properties. In thin films of these materials, however, substrate clamping is generally thought to limit the electric-field- or mechanical-force-driven responses to the local scale. Here, we report mechanical-force-induced large-area, non-local, collective ferroelastic domain switching in PbTiO₃ epitaxial thin films by tuning the misfit-strain to be near a phase boundary wherein c/a and a₁/a₂ nanodomains coexist. Phenomenological models suggest that the collective, c-a-c-a ferroelastic switching arises from the small potential barrier between the degenerate domain structures, and the large anisotropy of a and c

SUBMITTER: Lu X 

PROVIDER: S-EPMC6718682 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature