L-Aspartic Acid Capped CdS Quantum Dots as a High Performance Fluorescence Assay for Sliver Ions (I) Detection.

ABSTRACT: A new high performance fluorescence assay for detection of Ag+ based on CdS quantum dots (QDs) using L-Aspartic acid (L-Asp) as a stabilizer was proposed in this work. The CdS quantum dots conjugation with L-Aspartic acid (L-Asp@CdS QDs) were successfully synthesized via a simple hydrothermal process. The QDs have a fluorescence emission band maximum at 595 nm with a quantum yield of 11%. The obtained CdS QDs exhibit a particle size of 1.63 ± 0.28 nm and look like quantum dot flowers. Basically, the fluorescence intensity of L-Asp@CdS QDs can be enhanced only upon addition of Ag+ and a redshift in the fluorescence spectrum was observed. Under optimum conditions, the fluorescence enhancement of L-Asp@CdS QDs appeared to exhibit a good linear relationship in between 100-7000 nM (R2 = 0.9945)

SUBMITTER: Wang Z 

PROVIDER: S-EPMC6724099 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature