Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation.

ABSTRACT: A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral non-racemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.

SUBMITTER: Szymaniak AA 

PROVIDER: S-EPMC6726405 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature