Kinetic study of catalytic CO₂ hydration by metal-substituted biomimetic carbonic anhydrase model complexes.

ABSTRACT: The rapid rise of the CO₂ level in the atmosphere has spurred the development of CO₂ capture methods such as the use of biomimetic complexes that mimic carbonic anhydrase. In this study, model complexes with tris(2-pyridylmethyl)amine (TPA) were synthesized using various transition metals (Zn²⁺, Cu²⁺ and Ni²⁺) to control the intrinsic proton-donating ability. The pK_a of the water coordinated to the metal, which indicates its proton-donating ability, was determined by potentiometric pH titration and found to increase in the order [(TPA)Cu(OH₂)]²⁺ < [(TPA)Ni(OH₂)]²⁺ < [(TPA)Zn(OH₂)]²⁺. The effect of pK_a on the CO₂ hydration rate was investi

SUBMITTER: Park D 

PROVIDER: S-EPMC6731748 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature