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Grafting Polymers onto Carbon Nitride via Visible-Light-Induced Photofunctionalization.

ABSTRACT: Metal-free graphitic carbon nitride (g-CN) has attracted significant attention recently due to its multiple applications, such as photocatalysis, energy storage and conversion, and biomaterials, albeit formation of g-CN films is challenging. Herein, a "grafting to" route to graft polymer brushes onto g-CN via visible-light irradiation is described. Afterward, g-CN/polymer films can be obtained through spin coating on glass substrates. As such, the present material provides an improved process toward further application of g-CN in thin films. Moreover, an improved dispersibility in organic solvent was realized after grafting and functional groups (such as epoxides) were introduced to g-CN. Subsequently, the epoxy groups were utilized for further functionalization to adjust the surface polarity.

SUBMITTER: Cao Q

PROVIDER: S-EPMC6750929 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Grafting Polymers onto Carbon Nitride via Visible-Light-Induced Photofunctionalization.

Cao Qian Q Kumru Baris B Antonietti Markus M Schmidt Bernhard V K J BVKJ

Macromolecules 20190620 13

Metal-free graphitic carbon nitride (g-CN) has attracted significant attention recently due to its multiple applications, such as photocatalysis, energy storage and conversion, and biomaterials, albeit formation of g-CN films is challenging. Herein, a "grafting to" route to graft polymer brushes onto g-CN via visible-light irradiation is described. Afterward, g-CN/polymer films can be obtained through spin coating on glass substrates. As such, the present material provides an improved process to ...[more]

PMID: 31543549

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