Synthesis, Thermal Properties, and Rheological Characteristics of Indole-Based Aromatic Polyesters.

ABSTRACT: Currently, there is an intensive development of bio-based aromatic building blocks to replace fossil-based terephthalates used for poly(ethylene terephthalate) production. Indole is a ubiquitous aromatic unit in nature, which has great potential as a bio-based feedstock for polymers or plastics. In this study, we describe the synthesis and characterization of new indole-based dicarboxylate monomers with only aromatic ester bonds, which can improve the thermal stability and glass-transition temperature (T g) of the resulting polyesters. The new dicarboxylate monomers were polymerized with five aliphatic diols to yield 10 new polyesters with tunable chemical structures and physical properties. Particularly, the T g values of the obtained polyesters can be as high as 113 °C, as indicated by d

SUBMITTER: Arza CR 

PROVIDER: S-EPMC6751728 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature