Metal and Organic Templates Together Control the Size of Covalent Macrocycles and Cages.

ABSTRACT: Covalent macrocycles and three-dimensional cages were prepared by the self-assembly of di- or tritopic anilines and 2,6-diformylpyridine subcomponents around palladium(II) templates. The resulting 2,6-bis(imino)pyridyl-Pd^II motif contains a tridentate ligand, leaving a free coordination site on the Pd^II centers, which points inward. The binding of ligands to the free coordination sites in these assemblies was found to alter the product stability, and multitopic ligands could be used to control product size. Multitopic ligands also bridged metallomacrocycles to form higher-order supramolecular assemblies, which were characterized via NMR spectroscopy, mass spectrometry, and X-ray crystallography. An efficient method was developed to reduce the imine bonds to secondary

SUBMITTER: Lavendomme R 

PROVIDER: S-EPMC6756589 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature