Ca-Ag compounds in ethylene epoxidation reaction.

ABSTRACT: The ethylene epoxidation is a challenging catalytic process, and development of active and selective catalyst requires profound understanding of its chemical behaviour under reaction conditions. The systematic study on intermetallic compounds in the Ca-Ag system under ethylene epoxidation conditions clearly shows that the character of the oxidation processes on the surface originates from the atomic interactions in the pristine compound. The Ag-rich compounds Ca2Ag7 and CaAg2 undergo oxidation towards fcc Ag and a complex Ca-based support, whereas equiatomic CaAg and the Ca-rich compounds Ca5Ag3 and Ca3Ag in bulk remain stable under harsh ethylene epoxidation conditions. For the latter presence of water vapour in the gas stream leads to noticeable corrosion. Combining the experimental resu

SUBMITTER: Antonyshyn I 

PROVIDER: S-EPMC6758618 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature