Spontaneous generation of hydrogen peroxide from aqueous microdroplets.

ABSTRACT: We show H₂O₂ is spontaneously produced from pure water by atomizing bulk water into microdroplets (1 μm to 20 µm in diameter). Production of H₂O₂, as assayed by H₂O₂-sensitve fluorescence dye peroxyfluor-1, increased with decreasing microdroplet size. Cleavage of 4-carboxyphenylboronic acid and conversion of phenylboronic acid to phenols in microdroplets further confirmed the generation of H₂O₂ The generated H₂O₂ concentration was ∼30 µM (∼1 part per million) as determined by titration with potassium titanium oxalate. Changing the spray gas to O₂ or bubbling O₂ decreased the yield of H₂O₂ in microdroplets, indicating that pure water micro

SUBMITTER: Lee JK 

PROVIDER: S-EPMC6765303 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature