Energetics of the exchangeable quinone, Q_B, in Photosystem II.

ABSTRACT: Photosystem II (PSII), the light-driven water/plastoquinone photooxidoreductase, is of central importance in the planetary energy cycle. The product of the reaction, plastohydroquinone (PQH₂), is released into the membrane from the Q_B site, where it is formed. A plastoquinone (PQ) from the membrane pool then binds into the Q_B site. Despite their functional importance, the thermodynamic properties of the PQ in the Q_B site, Q_B, in its different redox forms have received relatively little attention. Here we report the midpoint potentials (E_m ) of Q_B in PSII from Thermosynechococcus elongatus using electron paramagnetic resonance (EPR) spectroscopy: E_m Q_B/Q_B^•-

SUBMITTER: De Causmaecker S 

PROVIDER: S-EPMC6765312 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature