Improved Solid-Contact Nitrate Ion Selective Electrodes Based on Multi-Walled Carbon Nanotubes (MWCNTs) as an Ion-to-Electron Transducer.

ABSTRACT: Possible improvement of the performance characteristics, reliability and selectivity of solid-contact nitrate ion-selective electrodes (ISE) (SC/NO3--ISE) is attained by the application of a nitron-nitrate (Nit+/NO3-) ion association complex and inserting multi-walled carbon nanotubes (MWCNTs) as an ion-to-electron transducer between the ion sensing membrane (ISM) and the electronic conductor glassy carbon (GC) substrate. The potentiometric performance of the proposed electrode revealed a Nernstian slope -55.1 ± 2.1 (r² = 0.997) mV/decade in the range from 8.0 × 10-8-1 × 10-2 M with a detection limit of 2.8 × 10-8 (1.7 ng/mL). Selectivity, repeatability and reproducibility of the proposed sensors were considerably improved as compared to the coated disc electrode (GC/NO3--ISE) without inse

SUBMITTER: Hassan SSM 

PROVIDER: S-EPMC6766930 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature