Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides.

ABSTRACT: The effective catalytic activity of organoaluminum compounds for the monohydroboration of carbodiimides has been demonstrated. Two aluminum complexes, 2 and 3, were synthesized and characterized. The efficient catalytic performances of four aluminum hydride complexes L¹ AlH₂ (L¹ =HC(CMeNAr)₂ , Ar=2,6-Et₂ C₆ H₃ ; 1), L² AlH₂ (NMe₃ ) (L² =o-C₆ H₄ F(CH=N-Ar), Ar=2,6-Et₂ C₆ H₃ ; 2), L³ AlH (L³ =2,6-bis(1-methylethyl)-N-(2-pyridinylmethylene)phenylamine; 3), and L⁴ AlH(NMe₃ ) (L⁴ =o-C₆ H₄ (N-Dipp)(CH=N-Dipp), Dipp=2,6-iPr₂ C₆

SUBMITTER: Shen Q 

PROVIDER: S-EPMC6771511 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature