Coordination Chemistry of P4 S3 and P4 Se3 towards the Iron Fragments [Fe(Cp)(CO)2 ]+ and [Fe(Cp)(PPh3 )(CO)].
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ABSTRACT: The complexes Ag(L)n [WCA] (L=P4 S3 , P4 Se3 , As4 S3 , and As4 S4 ; [WCA]=[Al(ORF )4 ]- and [F{Al(ORF )3 }2 ]- ; RF =C(CF3 )3 ; WCA=weakly coordinating anion) were tested for their performance as ligand-transfer reagents to transfer the poorly soluble nortricyclane cages P4 S3 , P4 Se3 , and As4 S3 as well as realgar As4 S4 to different transition-metal fragments. As4 S4 and As4 S3 with the poorest solubility did not yield complexes. However, the more so
SUBMITTER: Weis P
PROVIDER: S-EPMC6771638 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
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