A General and Air-tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis.

ABSTRACT: While current M⁰ /M^II based polymerization strategies largely focus on fine-tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air- and moisture stable dinuclear Pd^I catalyst. The method is operationally simple, robust and tolerant to air.

SUBMITTER: Magnin G 

PROVIDER: S-EPMC6771708 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature