Synthesis of clathrate cerium superhydride CeH₉ at 80-100 GPa with atomic hydrogen sublattice.

ABSTRACT: Hydrogen-rich superhydrides are believed to be very promising high-T_c superconductors. Recent experiments discovered superhydrides at very high pressures, e.g. FeH₅ at 130 GPa and LaH₁₀ at 170 GPa. With the motivation of discovering new hydrogen-rich high-T_c superconductors at lowest possible pressure, here we report the prediction and experimental synthesis of cerium superhydride CeH₉ at 80-100 GPa in the laser-heated diamond anvil cell coupled with synchrotron X-ray diffraction. Ab initio calculations were carried out to evaluate the detailed chemistry of the Ce-H system and to understand the structure, stability and superconductivity of CeH₉. CeH₉ crystallizes in a P6₃/mmc clathrate structure with a

SUBMITTER: Salke NP 

PROVIDER: S-EPMC6773858 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature