Tracking Electrical Fields at the Pt/H₂O Interface during Hydrogen Catalysis.

ABSTRACT: We quantify changes in the magnitude of the interfacial electric field under the conditions of H₂/H⁺ catalysis at a Pt surface. We track the product distribution of a local pH-sensitive, surface-catalyzed nonfaradaic reaction, H₂ addition to cis-2-butene-1,4-diol to form n-butanol and 1,4-butanediol, to quantify the concentration of solvated H⁺ at a Pt surface that is constantly held at the reversible hydrogen electrode potential. By tracking the surface H⁺ concentration across a wide range of pH and ionic strengths, we directly quantify the magnitude of the electrostatic potential drop at the Pt/solution interface and establish that it increases by ∼60 mV per unit increase in pH. These results provide direct insight into

SUBMITTER: Ryu J 

PROVIDER: S-EPMC6777043 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature