Synthesis of Two Mononuclear Schiff Base Metal (M = Fe, Cu) Complexes: MOF Structure, Dye Degradation, H₂O₂ Sensing, and DNA Binding Property.

ABSTRACT: O-Vanillin and ethylenediamine were used for the synthesis of N,N'-bis(O-vanillinidene)ethylenediamine (O-VEDH₂) Schiff base ligand, which was characterized by UV-visible and ¹H NMR spectroscopy. The Schiff base ligand O-VEDH₂ has been employed to synthesize novel [C₁₈H₂₂FeN₂O₆]NO₃ (1) and C₁₈H₁₆CuN₂O₅ (2) complexes by the simple slow evaporation method. The single crystals were characterized by X-ray crystallography, as well as Fourier-transform infrared and UV-visible spectroscopy techniques. Complexes 1 and 2 crystallize in monoclinic and orthorhombic space groups with P121/n1 (14) and Pnma (62)

SUBMITTER: Ghosh MK 

PROVIDER: S-EPMC6777120 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature