A microscopic look at the Johari-Goldstein relaxation in a hydrogen-bonded glass-former.

ABSTRACT: Understanding the glass transition requires getting the picture of the dynamical processes that intervene in it. Glass-forming liquids show a characteristic decoupling of relaxation processes when they are cooled down towards the glassy state. The faster (β_JG) process is still under scrutiny, and its full explanation necessitates information at the microscopic scale. To this aim, nuclear γ-resonance time-domain interferometry (TDI) has been utilized to investigate 5-methyl-2-hexanol, a hydrogen-bonded liquid with a pronounced β_JG process as measured by dielectric spectroscopy. TDI probes in fact the center-of-mass, molecular dynamics at scattering-vectors corresponding to both inter- and intra-molecular distances. Our measurements demonstrate that, in the undercooled

SUBMITTER: Caporaletti F 

PROVIDER: S-EPMC6778113 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature