A Nontrigonal Tricoordinate Phosphorus Ligand Exhibiting Reversible "Nonspectator" L/X-Switching.

ABSTRACT: We report here a "nonspectator" behavior for an unsupported L-function σ³ -P ligand (i.e. P{N[o-NMe-C₆ H₄ ]₂ }, 1a) in complex with the cyclopentadienyliron dicarbonyl cation (Fp⁺ ). Treatment of 1a⋅Fp⁺ with [(Me₂ N)₃ S][Me₃ SiF₂ ] results in fluoride addition to the P-center, giving the isolable crystalline fluorometallophosphorane 1a^F ⋅Fp that allows a crystallographic assessment of the variance in the Fe-P bond as a function of P-coordination number. The nonspectator reactivity of 1a⋅Fp⁺ is rationalized on the basis of electronic structure arguments and by comparison to trigonal analogue (Me₂ N)₃ P⋅Fp⁺ (i.e. 1b⋅Fp⁺

SUBMITTER: Cleveland GT 

PROVIDER: S-EPMC6779506 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature