A Guanidine-Based Superbase as Efficient Chemiluminescence Booster.
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ABSTRACT:
SUBMITTER: Geiselhart CM
PROVIDER: S-EPMC6786995 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Publications
A Guanidine-Based Superbase as Efficient Chemiluminescence Booster.
Geiselhart Christina M CM Schmitt Christian W CW Jöckle Philipp P Mutlu Hatice H Barner-Kowollik Christopher C
Scientific reports 20191010 1
We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase's properties as peroxidase mimetic and bifunctional coreactant. The herein established concept allows for CL enabling molecules (superbases) to be readily implemented in larger molecular structures, including in polymers. ...[more]
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