Highly Selective and Sensitive Detection of PO4 3- Ions in Aqueous Solution by a Luminescent Terbium Metal-Organic Framework.

ABSTRACT: A luminescent terbium metal-organic framework [Tb(HPIA-)(PIA2-)(H2O)2] (Tb-MOF), synthesized by a lanthanide metal ion (Tb3+) and nitric heterocyclic carboxylic acid ligands H2PIA (H2PIA = 5-(1H-pyrazol-3-yl)isophthalic-acid), was structurally characterized as a three-dimensional skeleton structure in which layered coordination frameworks are connected by hydrogen bonds. Based on the antenna effect, Tb-MOF can emit bright green fluorescence under 254 nm excitation, and the fluorescence emission presents excellent durability in aqueous solutions among a wide pH range. Moreover, the structure of Tb-MOF also possesses outstanding thermal stabilities. In some ways, PO4 3- and its derivatives are thought to be a kind of pollutant ion causing series environmental and health problems. The as-synt

SUBMITTER: Zhao S 

PROVIDER: S-EPMC6787892 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature