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Understanding Reaction Kinetics by Tailoring Metal Co-catalysts of the BiVO4 Photocatalyst.


ABSTRACT: In this study, the reaction mechanisms of metal-semiconductor composites used as photocatalysts were demonstrated by first preparing bismuth vanadate (BiVO4) and then performing photodeposition of metal nanoparticles. The photocatalytic activity of metal-BiVO4 (M-BiVO4, where M = Pt, Au, Ag) composites were evaluated through dye decomposition under UV-vis irradiation. The photocatalytic efficiency was significantly enhanced after Pt deposition as compared to other M-BiVO4 composites. The size or shape of BiVO4 was not the main factor for the efficiency of Pt-BiVO4. However, a deposited Pt co-catalyst was essential for the photocatalytic decomposition of dye on the BiVO4 surface. Radical scavengers were employed to elucidate the reaction mechanism during the photocatalytic reaction with the

SUBMITTER: Choe HR 

PROVIDER: S-EPMC6788043 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature