Nanoscale mapping of chemical composition in organic-inorganic hybrid perovskite films.

ABSTRACT: Lead-based organic-inorganic hybrid perovskite (OIHP) solar cells can attain efficiencies over 20%. However, the impact of ion mobility and/or organic depletion, structural changes, and segregation under operating conditions urge for decisive and more accurate investigations. Hence, the development of analytical tools for accessing the grain-to-grain OIHP chemistry is of great relevance. Here, we used synchrotron infrared nanospectroscopy (nano-FTIR) to map individual nanograins in OIHP films. Our results reveal a spatial heterogeneity of the vibrational activity associated to the nanoscale chemical diversity of isolated grains. It was possible to map the chemistry of individual grains in CsFAMA [Cs_0.05FA_0.79MA_0.16Pb(I_0.83Br_0.17)₃

SUBMITTER: Szostak R 

PROVIDER: S-EPMC6814396 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature