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Crystal structure of a two-dimensional coordination polymer of formula [Zn(NDC)(DEF)] (H2NDC is naphthalene-2,6-di-carb-oxy-lic acid and DEF is N,N-di-ethyl-formamide).

ABSTRACT: A zinc metal-organic framework, namely poly[bis-(N,N-di-ethyl-formamide)(μ4-naphthalene-2,6-di-carboxyl-ato)(μ2-naphthalene-2,6-di-carboxyl-ato)dizinc(II)], [Zn(C12H6O4)(C15H11NO)] n , built from windmill-type secondary building units and forming zigzag shaped two-dimensional stacked layers, has been solvothermally synthesized from naphthalene-2,6-di-carb-oxy-lic acid and zinc(II) acetate as the metal source in N,N-di-ethyl-formamide containing small amounts of formic acid.

SUBMITTER: Saffon-Merceron N

PROVIDER: S-EPMC6829708 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of a two-dimensional coordination polymer of formula [Zn(NDC)(DEF)] (H2NDC is naphthalene-2,6-di-carb-oxy-lic acid and DEF is N,N-di-ethyl-formamide).

Saffon-Merceron Nathalie N Vigroux Alain A Hoffmann Pascal P

Acta crystallographica. Section E, Crystallographic communications 20191029 Pt 11

A zinc metal-organic framework, namely poly[bis-(N,N-di-ethyl-formamide)(μ4-naphthalene-2,6-di-carboxyl-ato)(μ2-naphthalene-2,6-di-carboxyl-ato)dizinc(II)], [Zn(C12H6O4)(C15H11NO)] n , built from windmill-type secondary building units and forming zigzag shaped two-dimensional stacked layers, has been solvothermally synthesized from naphthalene-2,6-di-carb-oxy-lic acid and zinc(II) acetate ...[more]

PMID: 31709104

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