Crystal structures and hydrogen-bonding analysis of a series of solvated ammonium salts of molybdenum(II) chloride clusters.

ABSTRACT: Charge-assisted hydrogen bonding plays a significant role in the crystal structures of solvates of ionic com-pounds, especially when the cation or cations are primary ammonium salts. We report the crystal structures of four ammonium salts of molybdenum halide cluster solvates where we observe significant hydrogen bonding between the solvent molecules and cations. The crystal structures of bis-(anilinium) octa-μ3-chlorido-hexa-chlorido-octa-hedro-hexa-molybdate N,N-di--methyl-formamide tetra-solvate, (C6H8N)2[Mo6Cl8Cl6]·4C3H7NO, (I), p-phenyl-enedi-ammonium octa-μ3-chlorido-hexa-chlorido-octa-hedro-hexa-mol-yb-date N,N-di-methyl-formamide hexa-solvate, (C6H10N2)[Mo6Cl8Cl6]·6C3H7NO, (II), N,N'-(1,4-phenyl-ene)bis-(propan-2-iminium) octa-μ3-chlorido-hexa-chlo-rido-octa-hedro-hexa-molybdate ac

SUBMITTER: Johnston DH 

PROVIDER: S-EPMC6829717 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature