Nuclear-spin-pattern control of electron-spin dynamics in a series of V(iv) complexes.

ABSTRACT: Achieving control of phase memory relaxation times (T m) in metal ions is an important goal of molecular spintronics. Herein we provide the first evidence that nuclear-spin patterning in the ligand shell is an important handle to modulate T m in metal ions. We synthesized and studied a series of five V(iv) complexes with brominated catecholate ligands, [V(C6H4-n Br n O2)3]2- (n = 0, 1, 2, and 4), where the 79/81Br and 1H nuclear spins are arranged in different substitutional patterns. High-field, high-frequency (120 GHz) pulsed electron paramagnetic resonance spectroscopic analysis of this series reveals a pattern-dependent variation in T m for the V(iv) ion. Notably, we show that it is possible for two molecules to have starkly different (by 50%) T m values despite the same chemical compo

SUBMITTER: Jackson CE 

PROVIDER: S-EPMC6839508 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature