Modular supramolecular dimerization of optically tunable extended aryl viologens.

ABSTRACT: Cucurbit[8]uril (CB[8]) mediated assembly of extended aryl viologens (EVs) into optically tunable dimers is reported for the first time. We show that the modular design and synthesis of a new class of π-conjugated viologen derivatives with rigid aromatic or heteroaromatic bridging units as well as electron donating molecular recognition motifs enable their self-assembly into 2 : 2 complexes with CB[8]. The quantitative dimerization process involving these two molecular components in an aqueous solution enables excimer-like interactions between closely packed charged guests giving rise to distinct spectroscopic behavior. The nature of these dimers (CB[8]₂·(EV[X]R)₂) in the ground and excited states was characterized by NMR, isothermal titration calorimetry, and steady-

SUBMITTER: Olesinska M 

PROVIDER: S-EPMC6849629 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature