Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands.
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ABSTRACT: Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U[double bond, length as m-dash]N[double bond, length as m-dash]U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(( t BuO)3SiO)3U}2(μ-N)], [NBu4]-1, and [NBu4][((Me3Si)2N)3U}2(μ-N)], 2, were synthesised by reacting NBu4N3 with the U3+ complexes, [U(OSi(O t Bu)3)2(μ-OSi(O t Bu)3)]2 and [U(N(SiMe3)2)3], respectively. Oxidation of 2 with
SUBMITTER: Palumbo CT
PROVIDER: S-EPMC6853081 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
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