A sodium-ion sulfide solid electrolyte with unprecedented conductivity at room temperature.

ABSTRACT: Solid electrolytes are key materials to enable solid-state rechargeable batteries, a promising technology that could address the safety and energy density issues. Here, we report a sulfide sodium-ion conductor, Na_2.88Sb_0.88W_0.12S₄, with conductivity superior to that of the benchmark electrolyte, Li₁₀GeP₂S₁₂. Partial substitution of antimony in Na₃SbS₄ with tungsten introduces sodium vacancies and tetragonal to cubic phase transition, giving rise to the highest room-temperature conductivity of 32 mS cm^-1 for a sintered body, Na_2.88Sb_0.88W_0.12S₄. Moreover, this sulfide possesses additional advantages including stability against humid atmosp

SUBMITTER: Hayashi A 

PROVIDER: S-EPMC6868223 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature