Single Atomic Cu-N₂ Catalytic Sites for Highly Active and Selective Hydroxylation of Benzene to Phenol.

ABSTRACT: Searching for an efficient single-atom catalyst for benzene hydroxylation to phenol is of critical importance, but it still remains a challenge. Herein, a single-atom catalyst with unique Cu-N₂ moieties (Cu₁-N₂/HCNS) was prepared and confirmed by HAADF-STEM and EXAFS. Turnover number (TON) over Cu₁-N₂/HCNS (6,935) is 3.4 times of Cu₁-N₃/HCNS (2,034) under the same reaction conditions, and both exhibit much higher phenol selectivity (close to 99%) and stability compared with Cu nanoparticles and nanoclusters. Experiments and DFT calculations reveal that atomically dispersed Cu species are active sites for benzene hydroxylation to phenol, and the Cu-N₂ is more active than Cu-N₃ owing to its muc

SUBMITTER: Zhang T 

PROVIDER: S-EPMC6880104 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature