Synthesis, Structural, Linear, and Nonlinear Optical Studies of Inorganic-Organic Hybrid Semiconductors (R-C₆H₄CHCH₃NH₃)₂PbI₄, (R = CH₃, Cl).

ABSTRACT: Synthesis, crystal structure, and optical properties of two-dimensional (2D) layered structurally slightly different inorganic-organic (IO) hybrid semiconductors (R-C₆H₄C₂H₄NH₃)₂PbI₄ (R = CH₃, Cl) are presented. They are naturally self-assembled systems where two (RNH₃)⁺ moieties are sandwiched between two infinitely extended 2D layers of the [PbI₆]^4- octahedral network and treated as natural IO multiple quantum wells. While the former compound crystallizes into an orthorhombic system in the Cmc2₁ space group, the latter crystallizes into a monoclinic system in the space group P2₁/c. As a thin film, they are well-orie

SUBMITTER: Adnan M 

PROVIDER: S-EPMC6881839 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature