Iron anode mediated transformation of selenate in sand columns.

ABSTRACT: Removal of aqueous selenate by iron electrolysis is investigated using sand-packed column experiments under a flowing condition. An iron anode generates ferrous ions, while cathode produces hydroxide, thus producing ferrous hydroxide capable of reducing selenate to elemental selenium. Additionally, siderite could reduce selenate or selenite to elemental selenium. The removal rate of selenate is proportional to the contact time and the yield of ferrous hydroxide or ferrous carbonate. At a sequence of anode-cathode, the transformation of selenate mostly occurs in the zone after cathode. An operation of 48 h electrolysis finally transforms 82.2% of selenate at 0.2 mM of initial concentration, 1.8 m/day of seepage velocity and 1.26 mA/cm(2) of current density. A longer reactive zone after cath

SUBMITTER: Baek K 

PROVIDER: S-EPMC6886739 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature