Crystal structure of tris-[bis-(2,6-diiso-propyl-phen-yl) phosphato-κO]penta-kis-(methanol-κO)europium methanol monosolvate.

ABSTRACT: The mononuclear title complex, [Eu(C₂₄H₃₄O₄P)₃(CH₄O)₅]·CH₄O, (1), has been obtained as a minor product in the reaction between EuCl₃(H₂O)₆ and lithium bis-(2,6-diiso-propyl-phen-yl) phosphate in a 1:3 molar ratio in a methanol medium. Its structure exhibits monoclinic (P2₁/c) symmetry at 120 K and is isostructural with the La, Ce and Nd analogs reported previously [Minyaev et al. (2018a ▸). Acta Cryst. C74, 590-598]. In (1), all three bis-(2,6-diiso-propyl-phen-yl) phosphate ligands display the terminal κ¹ O-coordination mode. All of the hy-droxy H atoms are involved in O-H⋯O hydrogen bonding, exhi

SUBMITTER: Kalugin AE 

PROVIDER: S-EPMC6895930 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature