The varied structures of cobalt(II)-pyridine (py)-sulfate: [Co(SO₄)(py)₄] _n , [Co₂(SO₄)₂(py)₆] _n , and [Co₃(SO₄)₃(py)₁₁] _n.

ABSTRACT: The solid-state structures of two cobalt-pyridine-sulfate compounds, namely catena-poly[[tetra-kis-(pyridine-κN)cobalt(II)]-μ-sulfato-κ² O:O'], [Co(SO₄)(C₅H₅N)₄] _n , (1), and catena-poly[[tetra-kis-(pyridine-κN)cobalt(II)]-μ-sulfato-κ³ O:O',O''-[bis-(pyridine-κN)cobalt(II)]-μ-sulfato-κ³ O,O':O''] _n , [Co₂(SO₄)₂(C₅H₅N)₆] _n , (2), are reported. Compound (1) displays a polymeric structure, with infinite chains of Co^II cations adopting octa-hedral N₄O₂ coord

SUBMITTER: Park AM 

PROVIDER: S-EPMC6895941 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature