Controlling the Reactivity of the [P₈ W₄₈ O₁₈₄ ]^40- Inorganic Ring and Its Assembly into POMZite Inorganic Frameworks with Silver Ions.

ABSTRACT: The construction of pure-inorganic framework materials with well-defined design rules and building blocks is challenging. In this work, we show how a polyoxometalate cluster with an integrated pore, based on [P₈ W₄₈ O₁₈₄ ]^40- (abbreviated as {P₈ W₄₈ }), can be self-assembled into inorganic frameworks using silver ions, which both enable reactions on the cluster as well as link them together. The {P₈ W₄₈ } was found to be highly reactive with silver ions resulting in the in situ generation of fragments, forming {P₉ W₆₃ O₂₃₅ } and {P₁₀ W₆₆ O₂₅₁ } in compound (1) where these two clusters co-crystallize and are connected into a POMZite framew

SUBMITTER: Zhan CH 

PROVIDER: S-EPMC6900112 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature