Stability and Exchange Processes in Ionic Liquid/Porphyrin Composite Films on Metal Surfaces.

ABSTRACT: In light of increasing interest in the development of organic-organic multicomponent heterostructures on metals, this molecular-scale study investigates prototypical composite systems of ultrathin porphyrin and ionic liquid (IL) films on metallic supports under well-defined ultrahigh vacuum conditions. By means of angle-resolved X-ray photoelectron spectroscopy, we investigated the adsorption, stability, and thermal exchange of the resulting films after sequential physical vapor deposition of the free-base porphyrin 5,10,15,20-tetraphenylporphyrin, 2H-TPP, and the IL 1-methyl-3-octylimidazolium hexafluorophosphate, [C₈C₁Im][PF₆], on Ag(111) and Au(111). 2H-TPP shows two-dimensional growth of up to two closed molecular layers on Ag(111) and Au(111) and three

SUBMITTER: Lexow M 

PROVIDER: S-EPMC6913898 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature