A Simple Structure Conjugated Polymer for High Mobility Organic Thin Film Transistors Processed from Nonchlorinated Solvent.

ABSTRACT: Herein, a simple structure, nonchlorinated solvent processable high mobility donor-acceptor conjugated polymer, poly(2,5-bis(4-hexyldodecyl)-2,5-dihydro-3,6-di-2-thienyl-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-thiophene) (PDPPT3-HDO), is reported. The enhanced solubility in nonchlorinated solvent is realized based on a denser alkyl side chains strategy by incorporating small size comonomer thiophene. An associated benefit of thiophene comonomer is the remarkable structural simplicity of the resulting polymer, which is advantageous for industrial scaling up. The alkyl side chain density and structure of PDPPT3-HDO can efficiently control the self-assembly properties in solution and film. By bar coating from o-xylene solution, PDPPT3-HDO forms aligned films and exhibits high hole m

SUBMITTER: Wang Z 

PROVIDER: S-EPMC6918096 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature