Rational Design of a P2-Type Spherical Layered Oxide Cathode for High-Performance Sodium-Ion Batteries.

ABSTRACT: Sodium-ion batteries (SIBs) have been regarded as the most promising candidates for the next-generation energy storage devices owing to their low price and high abundance. However, the development of SIBs is mainly hindered by the instability of cathode materials. Here, we report a new P2-type manganese-rich cathode material, Na_0.66Li_0.18Mn_0.71Mg_0.21Co_0.08O₂ (P2-NaLiMMCO) with uniform spherical structure prepared via a simple solvothermal method and subsequent solid-state reaction. This P2-NaLiMMCO cathode material with uniform microsize secondary spheres and nanosize primary crystalline particles delivers a high initial discharge capacity of 166 mA h g^-1 and superior capacity retention, which are superior to most

SUBMITTER: Xiao J 

PROVIDER: S-EPMC6936088 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature