Synthesis and Structure of Methylsulfanyl Derivatives of Nickel Bis(Dicarbollide).

ABSTRACT: Symmetrically and unsymmetrically substituted methylsulfanyl derivatives of nickel(III) bis(dicarbollide) (Bu₄N)[8,8'-(MeS)₂-3,3'-Ni(1,2-C₂B₉H₁₀)₂], (Bu₄N)[4,4'-(MeS)₂-3,3'-Ni(1,2-C₂B₉H₁₀)₂], and (Bu₄N)[4,7'-(MeS)₂-3,3'-Ni(1,2-C₂B₉H₁₀)₂] were synthesized, starting from [Ni(acac)₂]₃ and the corresponding methylsulfanyl derivatives of nido-carborane (Bu₄N)[10-MeS-7,8-C₂B₉H₁₁] and (Bu₄N)[10-MeS-7,8-C₂B₉H₁₁]. Structures of the synthesized metallacarboranes were studied by single-cryst

SUBMITTER: Anufriev SA 

PROVIDER: S-EPMC6943677 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature