Extreme multi-point van der Waals interactions: isolable dimers of phthalocyanines substituted with pillar-like azaacenes.

ABSTRACT: How strong are van der Waals interactions in determining the final outcome of self-assembled structures of small molecular systems? Herein we report isolable phthalocyanine (Pc) dimers bound by π-π interactions between monomeric Pcs which can be handled as single entities. Pc dimers have been continuously investigated as one of the simplest models of Pc aggregates. Pcs were substituted with eight dihydrodiazapentacene (DHDAP) moieties on the periphery, which act as pillar-like π-planes and these molecules form H-type dimers with the help of synergetic π-π interactions between two co-facial Pc rings and among the pillar-like DHDAP moieties. The dimer structures were fully confirmed by 1D and 2D NMR, ESR, and electronic absorption measurements. The dissociation of these dimers was observed i

SUBMITTER: Saeki H 

PROVIDER: S-EPMC6993618 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature