5,7,12,14-Tetrafunctionalized 6,13-Diazapentacenes.

ABSTRACT: The synthesis, property evaluation, and single crystal X-ray structures of four 5,7,12,14-tetrafunctionalized diazapentacenes are presented. The synthesis of these compounds either starts from tetrabromo-N,N-dihydrodiazapentacene or from a diazapentacene tetraketone. Pd-catalyzed coupling or addition of a lithium acetylide gave the precursors that furnish, after further redox reactions, the diazapentacenes as stable crystalline materials. The performance of the tetraphenyl-substituted compound as n-channel semiconductor was evaluated in organic field effect transistors.

SUBMITTER: Xie G 

PROVIDER: S-EPMC7004126 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature