Photoreforming of Nonrecyclable Plastic Waste over a Carbon Nitride/Nickel Phosphide Catalyst.

ABSTRACT: With over 8 billion tons of plastic produced since 1950, polymers represent one of the most widely used-and most widely discarded-materials. Ambient-temperature photoreforming offers a simple and low-energy means for transforming plastic waste into fuel and bulk chemicals but has previously only been reported using precious-metal- or Cd-based photocatalysts. Here, an inexpensive and nontoxic carbon nitride/nickel phosphide (CN_x|Ni₂P) photocatalyst is utilized to successfully reform poly(ethylene terephthalate) (PET) and poly(lactic acid) (PLA) to clean H₂ fuel and a variety of organic chemicals under alkaline aqueous conditions. Ni₂P synthesized on cyanamide-functionalized carbon nitride is shown to promote efficient charge separation and

SUBMITTER: Uekert T 

PROVIDER: S-EPMC7007225 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature