Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes.

ABSTRACT: The non-oxidative catalytic dehydrogenation of light alkanes via C-H activation is a highly endothermic process that generally requires high temperatures and/or a sacrificial hydrogen acceptor to overcome unfavorable thermodynamics. This is complicated by alkanes being such poor ligands, meaning that binding at metal centers prior to C-H activation is disfavored. We demonstrate that by biasing the pre-equilibrium of alkane binding, by using solid-state molecular organometallic chemistry (SMOM-chem), well-defined isobutane and cyclohexane σ-complexes, [Rh(Cy₂PCH₂CH₂PCy₂)(η:η-(H₃C)CH(CH₃)₂][BAr^F₄] and [Rh(Cy₂PCH₂CH₂PCy₂)(η:η-C₆H₁₂

SUBMITTER: McKay AI 

PROVIDER: S-EPMC7007236 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature