Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency.

ABSTRACT: Monolayer-protected atomically precise silver clusters display low photoluminescence (PL) quantum yield (QY) and susceptibility under ambient conditions, and their chiroptical activities also remain underdeveloped. Here, we report enantiomers of an octahedral Ag6 cluster prepared via one-step synthesis using designed chiral ligands at ambient temperature. These clusters exhibit a highest PLQY (300 K) >95.0% and retain their structural integrity and emission up to 150°C in air. Atomically precise structural determination combined with photophysical and computational analysis revealed that thermally activated delayed fluorescence, observed in silver cluster systems, is responsible for the high PLQY, which combines chirality in excited states to generate strong circularly polarized luminescen

SUBMITTER: Han Z 

PROVIDER: S-EPMC7007243 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature