Thermally activated triplet exciton release for highly efficient tri-mode organic afterglow.

ABSTRACT: Developing high-efficient afterglow from metal-free organic molecules remains a formidable challenge due to the intrinsically spin-forbidden phosphorescence emission nature of organic afterglow, and only a few examples exhibit afterglow efficiency over 10%. Here, we demonstrate that the organic afterglow can be enhanced dramatically by thermally activated processes to release the excitons on the stabilized triplet state (T₁^*) to the lowest triplet state (T₁) and to the singlet excited state (S₁) for spin-allowed emission. Designed in a twisted donor-acceptor architecture with small singlet-triplet splitting energy and shallow exciton trapping depth, the thermally activated organic afterglow shows an efficiency up to 45%. This afterglow is an extr

SUBMITTER: Jin J 

PROVIDER: S-EPMC7016145 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature